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Metal buffering in plant cells highlights that a more oxidized redox state can generate an internal burst in available Zn 2+ 2+ With low-millimolar concentrations, a major contribution of glutathione (GSH), γ-glutamyl-cysteinyl-glycine (γ-ECG), to the cytosolic metal buffer appears feasible (Figures 1a and 2a) (apparent pK d of the Zn(GS) 2 complex ~8.1 at pH 7.7

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