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A We begin by calculating the millimoles of formic acid and formate present in 100 mL of the initial pH 3.95 buffer: The millimoles of H + in 5.00 mL of 1.00 M HCl is as follows: B Next, we construct a table of initial amounts, changes in amounts, and final amounts: The final amount of H + in solution is given as “∼0 mmol.” For the purposes of the stoichiometry calculation, this is essentially true, but remember that the point of the problem is to calculate the final [H + ] and thus the pH